Synthesis and Morphology of Polystyrene Macromonomer-4-Vinylpyridine Graft Copolymers.
نویسندگان
چکیده
منابع مشابه
Origin of the Difference in Order-Disorder Transition Temperature between Polystyrene-block-poly(2-vinylpyridine) and Polystyrene-block-poly(4-vinylpyridine) Copolymers
Three polystyrene-block-poly(2-vinylpyridine) (S2VP diblock) and three polystyrene-block-poly(4-vinylpyridine) (S4VP diblock) copolymers with varying molecular weights and block compositions were synthesized via anionic polymerization, and their order-disorder transition temperatures (TODTs) were determined using oscillatory shear rheometry and small-angle X-ray scattering (SAXS). It has been f...
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Polyoxometalates can serve as active components to induce and modulate the micellization behavior of polystyrene-block-poly(4-vinylpyridine).
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An efficient procedure to produce polyethene–graft–polystyrene (E-C3–graft–PS) copolymers by simple thermal treatment at 200 1C of polyethene (PE)-containing cyclopropane ring units (E-C3) in the presence of a high excess of styrene is reported. The high treatment temperature likely induces the breaking of the constrained cyclopropane rings, leading to the formation of radicals on the PE chains...
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The phase behavior of poly(styrene-block-2-vinylpyridine) copolymer solutions in an imidazolium bis(trifluoromethane)sulfonamide ([Im][TFSI]) ionic liquid has been studied using small-angle X-ray scattering (SAXS) and optical transmission characterization. Through scaling analysis of SAXS data, we demonstrate that the [Im][TFSI] ionic liquid behaves as a selective solvent toward one of the bloc...
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Grafting of vinyl monomers onto cellulose is an important tool for the modification of cellulose. Depending on the monomer grafted onto cellulose, it gains new properties. The grafting can be performed in heterogeneous or homogeneous medium. In the grafting performed in heterogeneous medium, the reaction is carried out in aqueous medium using a suitable initiator. As initiator, the radiation or...
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ژورنال
عنوان ژورنال: KOBUNSHI RONBUNSHU
سال: 1992
ISSN: 0386-2186,1881-5685
DOI: 10.1295/koron.49.547